South Australia 260 & 7 for 1 (Lyon 1-2) trail New South Wales 366 & 282 for 6 dec (Konstas 105, Henriques 52, Buckingham 3-48) by 382 runs

The teenage opener put New South Wales in control of their clash with South Australia at Cricket Central in Sydney, compiling 105 from 225 balls after making 152 in a breakout first innings.

"Obviously very special," Konstas said of the feat. "But hopefully we get the job done tomorrow and keep doing our basics well."

Having also missed a stumping in the first innings, Carey saved face with a diving catch that dismissed Nic Maddinson and continued the opener's meagre start to his second stint at NSW.

But Konstas nevertheless made the visitors pay. He brought up his half-century off Lloyd Pope in the 37th over with a four that rushed past extra cover so fast that Jordan Buckingham needed to jump to avoid the fence as he chased the ball past the boundary.

South Australia managed to slow Konstas down after tea as batting partners fell around him.

"They had different plans, they were bowling a wider line," Konstas said. "I had to be a bit ruthless and cop my medicine a bit."

But the teenager finally brought his century up as the final hour of play approached, smacking a six over deep midwicket from Ben Manenti's bowling.

South Australia finally removed him, with McInerney sprinting to long-on to catch him off Pope.

Earlier, Lyon continued an impressive lead-in to the Test summer, finishing his first Shield innings of the summer with a five-for.

Lyon ripped through the South Australian tail to ensure they were back in the sheds inside the first hour on day three, all out for 260.

Nathan McAndrew skied Lyon to deep square leg before Pope nicked off two balls later and set the stage for NSW to extend their lead, which was already 106 runs at the innings break.

Lyon expects to play two more matches for NSW ahead of the five-match Test series against India that begins in Perth late next month.